My guess is that it comes from the order typically used for ledgers, which is Description followed by Quantity. So you might have a ship's manifest with entries like:
| sacks of barley | 130 |
| kegs of wine | 12 |
| pesos de ocha | 2,800 |
So the abbreviation Ps starts out on the left-hand-side too.
Funny: when movies in English are dubbed to Spanish, the Latin expression is expanded and translated also, placed before the number: "era el año del Señor 1212 cuando...". It sounds good as if it were an archaism (the normal way of speaking is "1212 después de cristo" or 1212 DC).